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The Calcium Curse — why a tungsten skarn fights back at the mill

Aug 9
18 min read

Updated: Sep 17


In the previous Samso Insights - Understanding Tungsten - Part 1- "Reading the Skarn — where tungsten hides in the contact", calcium was the hero: it trapped tungsten as scheelite and built the orebody. In this discussion, it becomes the villain. The same calcium leaves scheelite surrounded by look-alike minerals — calcite, fluorite, apatite — that are almost impossible to tell apart in a flotation cell. This is why a high-grade skarn can still be a hard business.

Samso Insights

Research Note

Understanding Tungsten - Part 2

Geology Series

WHAT THIS PIECE COVERS

1.00 WHY THE EFFORT IS WORTH IT

Tungsten in sixty seconds, and why anyone bothers with the difficulty.

2.00 WHERE TUNGSTEN LIVES - RECAP

Four deposit types, and why skarns lead.

3.00 THE ROOT PROBLEM

The calcium curse, stated in one idea.

4.00 THE TARGET

Getting from 1 per cent rock to a 65 per cent concentrate.

5.00 LEVER ONE

Physics first, gravity and magnetism.

6.00 LEVER TWO

Why flotation is unavoidable, and how it works.

7.00 THE REAGENT KIT, PART A

Collectors, and what makes them grab the scheelite.

8.00 THE REAGENT KIT, PART B

Depressants, and what holds the gangue down.

9.00 THE 80-YEAR-OLD HAMMER

The Petrov process, a 1940 answer still in use.

10.00 HOW REAL MINES COPE

The same problem, solved differently at every mine.

11.00 WHERE IT'S HEADING

Greener chemistry, and computers taking on some of the guesswork.

12.00 SAMSO CONCLUDING COMMENTS

So how do you actually treat a tungsten skarn?

1.00 — WHY THE EFFORT IS WORTH IT

Tungsten in sixty seconds

Before the challenge of processing, comes the reward. Tungsten stands out in metallurgy due to its exceptional properties: it has the highest melting point of any metal and a density close to that of gold. This makes it a preferred choice for cutting tools, armor, and aerospace applications. Additionally, tungsten is rare, difficult to recycle, hard to replace, and approximately 80% of it is sourced from China. This is why the EU considers it a critical raw material.

Figure 1: Tungsten's value sits in extreme physical properties and concentrated supply, not volume — global mine output is only ~82,000 t/yr.  Source: Foucaud et al. (2020), citing USGS (2019) and Audion & Labbé (2012).

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