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From villain to dividend — the fluorite hiding in tungsten skarns

Aug 16
13 min read

Updated: Sep 17


In Part 2, fluorite was the villain — the calcium look-alike that makes a tungsten concentrate so hard to clean. But fluorite (fluorspar) is itself a critical mineral. So the question writes itself: if you can separate it, is the troublemaker actually a second product? The literature says yes — with conditions. Here is the evidence, sourced.


Samso Insights

Research Note

Understanding Tungsten - Part 3

Samso Geology Series

WHAT THIS PIECE COVERS

1.00 THE PIVOT

One mineral, two destinies, and why the villain of Part 1 is worth a second look.

2.00 FLUORSPAR 101

What fluorite is, and why it is worth recovering at all.

3.00 WHY THE WEST CARES

A critical mineral with a concentrated supply chain.

4.00 THE GEOLOGICAL GIFT

The same fluids build both minerals, which is why they sit together.

5.00 THE PROCESSING PIVOT

One separation, two saleable concentrates.

6.00 THE EVIDENCE

What the published work actually demonstrates, and where it comes from.

7.00 THE HONEST CATCH

Grade is the whole game, and the gap between metspar and acidspar is wide.

8.00 THE VALUE PROOF-POINT

What OD6's Quinn project shows, and what it does not.

1.00 — THE PIVOT

One mineral, two destinies

As we conclude the Understanding Tungsten series, we come to balance out the view of why the skarn tungsten deposits dominate the space. In Part 2, we talked about the issues of processing tungsten with "contaminants" complicating the discussion. Everything in Part 2 treated fluorite (CaF₂) as the enemy, being the main gangue mineral whose surface is so close to scheelite's that fatty acids float both, diluting the tungsten concentrate. That is all true.

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